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Tomás Ramírez Reina, Dr. Svetlana Ivanova, Dr. Juan José Delgado, Dr. Ivan Ivanov, Dr. Vasko Idakiev, Dr. Tatyana Tabakova, Dr. Miguel Angel Centeno and Prof. José Antonio Odriozola Viability of Au/CeO2–ZnO/Al2O3 Catalysts for Pure Hydrogen Production by the Water–Gas Shift Reaction ChemCatChem 6

Version of Record online: 26 FEB 2014 | DOI: 10.1002/cctc.201300992

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Zinc booster: A series of gold catalysts supported on ZnO-promoted CeO2–Al2O3 are applied in the purification of H2 streams through the water–gas shift reaction. The addition of ZnO promotes the activity of an Au/CeO2/Al2O3 catalyst. This increase in activity is mainly associated with the enhanced O2 storage capacity of the Zn-containing solids. The prepared catalysts tolerate start–stop cycles, showing potential for industrial application.

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