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Dr. Christopher A. Smith, Prof. Henri Cramail and Dr. Thierry Tassaing Insights into the Organocatalyzed Synthesis of Urethanes in Supercritical Carbon Dioxide: An In Situ FTIR Spectroscopic Kinetic Study ChemCatChem 6

Version of Record online: 18 MAR 2014 | DOI: 10.1002/cctc.201301002

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Back to the FTIR: The most efficient organocatalysts have been identified for the reaction of alcohols with isocyanates in supercritical CO2 in a step towards a green process for polyurethane synthesis. The order of activity of the catalysts in supercritical CO2 does not always follow that observed in conventional media.

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