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Dr. Rachel S. Heath, Dr. Marta Pontini, Dr. Beatrice Bechi and Prof. Nicholas J. Turner Development of an R-Selective Amine Oxidase with Broad Substrate Specificity and High Enantioselectivity ChemCatChem 6

Article first published online: 22 JAN 2014 | DOI: 10.1002/cctc.201301008

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Nicotine rush: An R-selective amine oxidase based on 6-hydroxy-D-nicotine oxidase (6-HDNO) with broadened substrate scope and high enantioselectivity has been developed. The engineered 6-HDNO enzyme is applied to the preparative deracemization of a range of racemic amines to yield S-configured products, for example, (S)-nicotine, in high ee.

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