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Valerica Pandarus, Olivier Marion, Geneviève Gingras, Dr. François Béland, Rosaria Ciriminna and Dr. Mario Pagliaro SiliaCat Diphenylphosphine Palladium(II) Catalyzed Borylation of Aryl Halides ChemCatChem 6

Article first published online: 3 MAR 2014 | DOI: 10.1002/cctc.201301035

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Clean borylation for scale-up: With the easy access and broad availability of diverse borylated species, the Suzuki–Miyaura reaction has become routine in industry and in research labs. We report a new selective route for direct access to a diverse set of boronic acid pinacol esters over the sol–gel entrapped SiliaCat diphenylphosphine palladium(II) catalyst that can be easily scaled-up.

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