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Christoph Reiter, Sònia López-Molina, Bernhard Schmid, Dr. Christian Neiss, Prof. Dr. Andreas Görling and Prof. Dr. Svetlana B. Tsogoeva Michael Addition of N-Unprotected 2-Oxindoles to Nitrostyrene Catalyzed by Bifunctional Tertiary Amines: Crucial Role of Dispersion Interactions ChemCatChem 6

Version of Record online: 5 MAR 2014 | DOI: 10.1002/cctc.201301052

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The importance of being dispersed: Bifunctional thiourea- or sulfonamide-derived tertiary amines such as Takemoto′s catalyst catalyze the enantioselective nitro-Michael addition of N-unprotected 3-substituted 2-oxindoles to nitrostyrene in high yields and enantiomeric and diastereomeric ratios. DFT calculations including van der Waals corrections are performed for the stereoisomers.

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