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Kazuki Fukumoto, Dr. Akira Onoda, Dr. Eiichi Mizohata, Dr. Marco Bocola, Prof. Dr. Tsuyoshi Inoue, Prof. Dr. Ulrich Schwaneberg and Prof. Dr. Takashi Hayashi Rhodium-Complex-Linked Hybrid Biocatalyst: Stereo-Controlled Phenylacetylene Polymerization within an Engineered Protein Cavity ChemCatChem 6

Version of Record online: 13 FEB 2014 | DOI: 10.1002/cctc.201301055

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Hybrid biocatalysis, β in a barrel: The incorporation of a Rh complex into the cavity of the nitrobindin β-barrel scaffold through a covalent linkage provides a hybrid catalyst that promotes the polymerization of phenylacetylene. The appropriate structural optimization of the cavity by mutagenesis enhances the trans content of the polymer. PPA=Polyphenylacetylene.

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