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Dr. Fumitaka Hayashi, Prof. Masaaki Kitano, Dr. Toshiharu Yokoyama, Prof. Michikazu Hara and Prof. Hideo Hosono Surface Treatment for Conductive 12 CaO⋅7 Al2O3 Electride Powder by Rapid Thermal Annealing Processing and Its Application to Ammonia Synthesis ChemCatChem 6

Version of Record online: 5 MAR 2014 | DOI: 10.1002/cctc.201301061

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Hot and fast! Rapid thermal annealing enables the surface reconstruction of the [Ca24Al28O64]4+(e)4 electride without fatal particle sintering, which allows smooth electron transfer to a N2 molecule adsorbed on Ru nanoparticles. The surface area achieved (9–19 m2 g−1) is ≈10 times greater than that of solid-state-synthesized [Ca24Al28O64]4+(e)4.

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