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Li-Jun Gu, Cheng Jin, Rui Wang and Hong-Yan Ding Rhodium Catalyzed ortho-Cyanation of Arylphosphates with N-cyano-N-phenyl-p-toluenesulfonamide ChemCatChem 6

Version of Record online: 12 FEB 2014 | DOI: 10.1002/cctc.201301076

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A question of chelation: A rhodium-catalyzed cyanation of chelation assisted C[BOND]H bonds is described employing NCTS as an efficient cyanating reagent. The present method allowed the synthesis of various 2-cyanated arylphosphonate and related compounds in moderate to good yield.

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