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Dr. Carlos F. R. A. C. Lima, Ana S. M. C. Rodrigues, Dr. Vera L. M. Silva, Prof. Artur M. S. Silva and Prof. Luís M. N. B. F. Santos Role of the Base and Control of Selectivity in the Suzuki–Miyaura Cross-Coupling Reaction ChemCatChem 6

Version of Record online: 12 MAR 2014 | DOI: 10.1002/cctc.201301080

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Follow the organoborate road: Competition Suzuki–Miyaura reactions between two boronic acids with different pKa values reveal the link between acid–base chemistry and the reaction catalytic cycle. The results reveal that the borate path is the preferred route for transmetalation and thus confirm the role of the base in the reaction mechanism.

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