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Dr. Aysegul Ciftci, Seda Eren, Dr. D. A. J. Michel Ligthart and Prof. Emiel J. M. Hensen Platinum–Rhenium Synergy on Reducible Oxide Supports in Aqueous-Phase Glycerol Reforming ChemCatChem 6

Version of Record online: 11 MAR 2014 | DOI: 10.1002/cctc.201301096

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Re as a promoter, TiO2 too: Pt supported on TiO2 exhibits the highest activity in aqueous-phase reforming (APR) of glycerol relative to Pt supported on CeO2, CeZrO2, ZrO2, and activated carbon. Re promotion increases the rates of C[BOND]O bond cleavage and water gas shift (WGS) reaction and is least pronounced for Pt/TiO2, as the titania support already promotes dehydration and WGS steps.

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