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Dr. Karin Garcés, Dr. Francisco J. Fernández-Alvarez, Dr. Víctor Polo, Dr. Ralte Lalrempuia, Prof. Jesús J. Pérez-Torrente and Prof. Luis A. Oro Iridium-Catalyzed Hydrogen Production from Hydrosilanes and Water ChemCatChem 6

Version of Record online: 11 APR 2014 | DOI: 10.1002/cctc.201301107

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From hydrosilanes to hydrogen: The iridium(III) complex [Ir(H)(CF3SO3)(NSiN)(coe)] is an effective homogeneous catalyst precursor for hydrogen production from the hydrolysis of hydrosilanes (NSiN=fac-coordinated bis(pyridine-2-yloxy)methylsilyl, coe=cyclooctene).

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