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Shanyan Mo and Prof. Dr. Jiaxi Xu Chemospecific Intramolecular Buchner Reaction Catalyzed by Copper(II) Acetylacetonate ChemCatChem 6

Version of Record online: 3 APR 2014 | DOI: 10.1002/cctc.201400014

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Cheap as copper: Copper(II) acetylacetonate is an efficient catalyst in the intramolecular Buchner reaction of N-benzyl-2-cyano-2-diazoacetamides for the chemospecific synthesis of 9-aza-1-cyanobicyclo[5.3.0]deca-2,4,6-trien-10-one derivatives in moderate to excellent yields with a broad substrate scope.

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