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Zhengwen Cao, Prof. Dr. Heqing Jiang, Dr. Huixia Luo, Dr. Stefan Baumann, Dr. Wilhelm A. Meulenberg, Dr. Hartwig Voss and Prof. Dr. Jürgen Caro An Efficient Oxygen Activation Route for Improved Ammonia Oxidation through an Oxygen-Permeable Catalytic Membrane ChemCatChem 6

Article first published online: 18 MAR 2014 | DOI: 10.1002/cctc.201400048

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Got to get some activated oxygen through: By using an oxygen-permeable membrane, the activation of oxygen is separated from the catalytic oxidation, which suppresses the formation of nonselective surface molecular oxygen species that can cause low selectivity. A continuous flux of lattice oxygen through the membrane allows highly selective partial oxidation. As a result, the selectivity for NO in the oxidation of ammonia is improved.

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