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Anis Tlili, Johannes Schranck, Jola Pospech, Dr. Helfried Neumann and Prof. Dr. Matthias Beller Ruthenium-Catalyzed Hydroaroylation of Styrenes in Water through Directed C[BOND]H Bond Activation ChemCatChem 6

Version of Record online: 3 APR 2014 | DOI: 10.1002/cctc.201402031

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Three-Component Hydroaroylation: Hydroaroylation through C[BOND]H activation of (hetero)arenes bearing ortho-directing groups (DGs) proceeds in the presence of a ruthenium catalyst, carbon monoxide, and styrenes. The shown coupling process provides selective and atom-economic access to (hetero)- aromatic ketones.

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