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Dr. Michael Mehlhorn, Dr. Sebastian Schnur, Prof. Dr. Axel Groß and Prof. Dr. Karina Morgenstern Molecular-Scale Imaging of Water Near Charged Surfaces ChemElectroChem 1

Version of Record online: 24 JUL 2013 | DOI: 10.1002/celc.201300063

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So simple? Since the basic idea of ultrahigh-vacuum (UHV) electrochemical modeling emerged, it has been claimed that UHV model experiments are too simple because they do not include the electrode potential. This combined scanning tunneling microscopy and density functional theory study gives insight into the influence of the electric field on single molecules in the diffusive layer. A field reorients adsorbed water molecules on water bilayers on Cu(111) at a distance of about 1 nm from the surface.

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