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Dr. Yoshishige Okuno Theoretical Investigation of the Mechanism of the Baeyer-Villiger Reaction in Nonpolar Solvents Chemistry - A European Journal 3

Version of Record online: 20 JAN 2006 | DOI: 10.1002/chem.19970030208

Catalysis, substituent effect, isotope effect, and complex kinetics in the Baeyer-Villiger reaction are examined theoretically on the basis of ab initio molecular orbital calculations as well as existing experimental results. It is concluded that the mechanism of the reaction depends on both type of catalyst and substituent effect.

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