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Dario Braga, Lucia Maini, Marco Polito, Laurent Mirolo and Fabrizia Grepioni Assembly of Hybrid Organic–Organometallic Materials through Mechanochemical Acid–Base Reactions Chemistry - A European Journal 9

Version of Record online: 11 SEP 2003 | DOI: 10.1002/chem.200305017

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Grinding the organometallic complex [Fe(η5-C5H4COOH)2] as a solid polycrystalline material with a number of solid bases generates quantitatively the corresponding adducts held together by hydrogen-bonding interactions of the O[BOND]H⋅⋅⋅O, O[BOND]H⋅⋅⋅N, and O⋅⋅⋅H[BOND]N types. Crystallization from methanol in the presence of seeds of the ground sample allows the growth of single crystals of the adducts, whose structure can thus be determined and used in turn to characterize the polycrystalline materials obtained by the grinding process (see scheme).

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