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Amar H. Flood, Andrea J. Peters, Scott A. Vignon, David W. Steuerman, Hsian-Rong Tseng, Seogshin Kang, James R. Heath and J. Fraser Stoddart The Role of Physical Environment on Molecular Electromechanical Switching Chemistry - A European Journal 10

Article first published online: 24 NOV 2004 | DOI: 10.1002/chem.200401052

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No matter what the surroundings, be it solution, a self-assembled monolayer on gold, or a solid-state polymer matrix, the same molecular electromechanical switching mechanism is obeyed for bistable rotaxanes (see illustration) and bistable catenanes in appropriate settings. However, the kinetics and thermodynamic parameters change quite dramatically from one environment to another.

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