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Cornelis A. Kruithof, Miguel A. Casado, Gabriela Guillena, Maarten R. Egmond, Anca van der Kerk-van Hoof, Albert J. R. Heck, Robertus J. M. Klein Gebbink and Gerard van Koten Lipase Active-Site-Directed Anchoring of Organometallics: Metallopincer/Protein Hybrids Chemistry - A European Journal 11

Version of Record online: 13 OCT 2005 | DOI: 10.1002/chem.200500671

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An organometallic-complex/lipase hybridization method: p-Nitrophenol phosphonate esters have been used as anchoring units to incorporate organometallic pincer complexes into the active site of the lipase cutinase. Hybridization of cutinase with the organometallic phosphonates 13 results in organometallic pincer cutinase hybrids that contain exactly one transition-metal pincer complex at a predetermined position.

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