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Zhi-Bin Zhou, Hajime Matsumoto and Kuniaki Tatsumi Cyclic Quaternary Ammonium Ionic Liquids with Perfluoroalkyltrifluoroborates: Synthesis, Characterization, and Properties Chemistry - A European Journal 12

Article first published online: 3 JAN 2006 | DOI: 10.1002/chem.200500930

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Cyclic quaternary ammonium ionic liquids with perfluoroalkyltrifluoroborates ([RFBF3], RF=CF3, C2F5, nC3F7, nC4F9; see picture) were synthesized and characterized. Their properties, such as phase transitions, thermal stability, density, viscosity, conductivity, and electrochemical windows, are significantly affected by the identity of the cation and anion, the variation of the side chain of the cation, and the change of the length of perfluoroalkyl (RF) in [RFBF3].

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