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Karl-Christian Schwan, Alexey Y. Timoskin, Manfred Zabel and Manfred Scheer Lewis Base Stabilized Phosphanylborane Chemistry - A European Journal 12

Version of Record online: 27 APR 2006 | DOI: 10.1002/chem.200600185

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The first monomeric compound of phosphanylborane [H2PBH2⋅NMe3] (2), stabilized only by a Lewis base, has been synthesized, opening broader perspectives for subsequent reactions. Thus, reactions with different Lewis acids, novel main-group elements, or transition-metal-substituted phosphanylboranes become possible. In detailed studies, oxidation processes yielded boranylphosphine chalcogenides [H2P(Q)BH2⋅NMe3] (Q = S; Se) as well as a novel boranyl phosphonic acid [(HO)2P(O)BH2⋅NMe3].

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