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Leonard L. Tinker, Neal D. McDaniel, Peter N. Curtin, Courtney K. Smith, Michael J. Ireland and Stefan Bernhard Visible Light Induced Catalytic Water Reduction without an Electron Relay Chemistry - A European Journal 13

Version of Record online: 24 JUL 2007 | DOI: 10.1002/chem.200700480

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The long-lived triplet state of a cyclometalated IrIII complex was used to reduce protons from water photo-catalytically to H2. The kinetics of the hydrogen evolution were monitored with a novel photoreactor and a maximum quantum yield of 26 % was measured for this electron relay deficient system.

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