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Alberto Abad, Avelino Corma and Hermenegildo García Catalyst Parameters Determining Activity and Selectivity of Supported Gold Nanoparticles for the Aerobic Oxidation of Alcohols: The Molecular Reaction Mechanism Chemistry - A European Journal 14

Version of Record online: 23 NOV 2007 | DOI: 10.1002/chem.200701263

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Even nanoparticles need gold: The mechanism of alcohol oxidation by gold nanoparticles supported on nanoparticulated ceria, a general catalyst for aerobic alcohol oxidation (see scheme), has hydride transfer as the rate-determining step.

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