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Michael G. Organ, Mirvat Abdel-Hadi, Stephanie Avola, Igor Dubovyk, Niloufar Hadei, Eric Assen B. Kantchev, Christopher J. O'Brien, Mahmoud Sayah and Cory Valente Pd-Catalyzed Aryl Amination Mediated by Well Defined, N-Heterocyclic Carbene (NHC)–Pd Precatalysts, PEPPSI Chemistry - A European Journal 14

Article first published online: 25 JAN 2008 | DOI: 10.1002/chem.200701621

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A practical protocol for the amination of aryl chlorides and bromides catalyzed by Pd-PEPPSI precatalysts affords a range of sterically hindered and functionalized, drug-like aryl amines in good to excellent yield under strongly (tBuOK) or weakly basic (Cs2CO3) conditions.

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