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Silvia García-Rubín, Jesús A. Varela, Luis Castedo and Carlos Saá Recent Advances in “Formal” Ruthenium-Catalyzed [2+2+2] Cycloaddition Reactions of Diynes to Alkenes Chemistry - A European Journal 14

Article first published online: 2 SEP 2008 | DOI: 10.1002/chem.200801088

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A formal event in chemistry! “Formal” RuII-catalyzed [2+2+2] cycloaddition reactions of 1,6-diynes and alkenes were found to give bicyclic 1,3-cyclohexadienes (see scheme). The regio- and stereochemical course of the reaction depends on the substitution of the 1,6-diyne.

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