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Gerhard F. Swiegers, Junhua Huang, Robin Brimblecombe, Jun Chen, G. Charles Dismukes, Ulrich T. Mueller-Westerhoff, Leone Spiccia and Gordon G. Wallace Homogeneous Catalysts with a Mechanical (“Machine-like”) Action Chemistry - A European Journal 15

Article first published online: 6 APR 2009 | DOI: 10.1002/chem.200802396

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Molecular machines? The factors involved in and the fundamental nature of a “mechanical” action within molecular catalysis is explored in detail. Such mechanical homogeneous catalysts are rare but not unknown (see graphic). The spatial and temporal nature of their catalytic action is considered. Potential implications for mimicry of enzymes are discussed.

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