E-mail a Wiley Online Library Link

Mariham Y. Abraham, Yuzhong Wang, Yaoming Xie, Pingrong Wei, Henry F. Schaefer III, P. von R. Schleyer and Gregory H. Robinson Carbene Stabilization of Diarsenic: From Hypervalency to Allotropy Chemistry - A European Journal 16

Article first published online: 24 NOV 2009 | DOI: 10.1002/chem.200902840

Thumbnail image of graphical abstract

Diarsenic as a Lewis acid: An N-heterocyclic carbene stabilized diarsenic molecule [L:As[BOND]As:L] (L:=:C{N(2,6-iPr2C6H3)CH}2) (see scheme) has been prepared by potassium/graphite reduction of [L:AsCl3]. The nature of the bonding in this molecule was probed by DFT computations.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field