E-mail a Wiley Online Library Link

Valentine P. Ananikov, Konstantin A. Gayduk, Nikolay V. Orlov, Irina P. Beletskaya, Victor N. Khrustalev and Mikhail Yu. Antipin Two Distinct Mechanisms of Alkyne Insertion into the Metal–Sulfur Bond: Combined Experimental and Theoretical Study and Application in Catalysis Chemistry - A European Journal 16

Version of Record online: 28 JAN 2010 | DOI: 10.1002/chem.200902928

Thumbnail image of graphical abstract

Two different mechanisms of multiple carbon–carbon bond insertion into the metal–heteroatom bond have been studied. A five-coordinate metal complex resulted in product formation without preliminary ligand dissociation on the alkyne insertion stage. The results of the mechanistic study were utilized to construct a new catalytic reaction to form target vinyl sulfides with high yields (up to 99 %) and excellent selectivity (>99:1).

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field