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Laura Iturrate, Israel Sánchez-Moreno, Isabel Oroz-Guinea, Jesús Pérez-Gil and Eduardo García-Junceda Preparation and Characterization of a Bifunctional Aldolase/Kinase Enzyme: A More Efficient Biocatalyst for C[BOND]C Bond Formation Chemistry - A European Journal 16

Article first published online: 2 MAR 2010 | DOI: 10.1002/chem.200903096

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When one plus one is more than two: An engineered bifunctional enzyme can catalyze aldol addition reactions by using dihydroxyacetone (DHA; see scheme) as an initial ketone donor. This new enzyme is a more affordable, stable, and efficient biocatalyst than the multienzyme system composed of the free parent enzymes.

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