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Marc-André Beaulieu, Dr. Cyrille Sabot, Nabil Achache, Kimiaka C. Guérard and Prof. Dr. Sylvain Canesi An Oxidative Prins–Pinacol Tandem Process and its Application to the synthesis of (−)-Platensimycin Chemistry - A European Journal 16

Version of Record online: 25 AUG 2010 | DOI: 10.1002/chem.201001813

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Center stage: An oxidative Prins–pinacol tandem process mediated by a hypervalent iodine reagent has been accomplished. The strategy allows rapid access to highly functionalized spirocyclic cores (see scheme) present in many natural products. A first application to the formal synthesis of (−)-platensimycin has been achieved.

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