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Dr. Keiichi Katoh, Prof. Takashi Kajiwara, Prof. Motohiro Nakano, Prof. Yasuhiro Nakazawa, Prof. Wolfgang Wernsdorfer, Prof. Naoto Ishikawa, Prof. Brian K. Breedlove and Prof. Masahiro Yamashita Magnetic Relaxation of Single-Molecule Magnets in an External Magnetic Field: An Ising Dimer of a Terbium(III)–Phthalocyaninate Triple-Decker Complex Chemistry - A European Journal 17

Article first published online: 7 DEC 2010 | DOI: 10.1002/chem.201002026

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A single magnet in a triple decker! TbIII–phthalocyaninate triple-decker 1, which has a center of symmetry, showed two magnetic relaxation processes in the low-temperature region in the presence of a direct current (dc) magnetic field. These results suggest that the single-molecule magnet/magnetic properties of 1 undergo a significant transition in a dc magnetic field.

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