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Dr. Hai-Long Jiang, Qi-Pu Lin, Dr. Tomoki Akita, Bo Liu, Dr. Hironori Ohashi, Dr. Hiroshi Oji, Dr. Tetsuo Honma, Prof. Dr. Takashi Takei, Prof. Dr. Masatake Haruta and Prof. Dr. Qiang Xu Ultrafine Gold Clusters Incorporated into a Metal–Organic Framework Chemistry - A European Journal 17

Article first published online: 3 DEC 2010 | DOI: 10.1002/chem.201002088

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Trapping gold! A novel porous metal–organic framework (MOF) with an unprecedented hexagonal (4,8)-connected topology has been assembled and characterized. By employing the resultant MOF as a host, for the first time, ultrafine Au clusters with an average atom number of 2.5 were successfully prepared and incorporated into the pores of the MOF through a simple surfactant-free method (see graphic).

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