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Prof. Dr. Takashi Kajiwara, Prof. Dr. Motohiro Nakano, Kohei Takahashi, Dr. Shinya Takaishi and Prof. Dr. Masahiro Yamashita Structural Design of Easy-Axis Magnetic Anisotropy and Determination of Anisotropic Parameters of LnIII[BOND]CuII Single-Molecule Magnets Chemistry - A European Journal 17

Article first published online: 10 DEC 2010 | DOI: 10.1002/chem.201002434

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Let's stick together: Four dinuclear LnIII[BOND]CuII complexes (Ln=Tb, Dy, Ho, Er) were synthesized to investigate the relationship between their respective magnetic and ligand-field anisotropies. A uni-axial ligand field (see figure) was achieved by using three phenoxo oxygen atoms in these complexes, of which detailed single-molecule magnet behaviors and the determination of magnetic anisotropy parameters were discussed.

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