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Prof. Francesco P. Ballistreri, Dr. Salvatore Gentile, Dr. Andrea Pappalardo, Prof. Gaetano A. Tomaselli, Sanghamitra Pradhan and Prof. Lorenzo Di Bari Reversible Mutarotation in a Macrocyclic Ytterbium Complex Chemistry - A European Journal 17

Article first published online: 13 DEC 2010 | DOI: 10.1002/chem.201002447

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Helices are a-changing: In a macrocyclic complex of late lanthanides, a slow ligand conformational rearrangement in solution leads to helicity inversion that can be reverted by slow solvent evaporation and provides a circular dichroism time-marker (see graphic).

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