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Dr. M. Caterina Lubinu, Dr. Lidia De Luca, Prof. Giampaolo Giacomelli and Dr. Andrea Porcheddu Microwave-Promoted Selective Mono-N-Alkylation of Anilines with Tertiary Amines by Heterogeneous Catalysis Chemistry - A European Journal 17

Version of Record online: 24 NOV 2010 | DOI: 10.1002/chem.201002704

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A palladium-catalyzed N-alkylation of anilines with tertiary amines that occurs under heterogeneous transfer-hydrogenation conditions has been developed (see scheme). This protocol of transamination, which uses a relatively cheap and easily recyclable heterogeneous catalyst, can be efficiently applied to different substrates and is suitable for large-scale preparations.

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