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Dr. Valérie Maraval, Dr. Léo Leroyer, Dr. Aya Harano, Cécile Barthes, Alix Saquet, Carine Duhayon, Prof. Teruo Shinmyozu and Prof. Remi Chauvin 1,4-Dialkynylbutatrienes: Synthesis, Stability, and Perspectives in the Chemistry of carbo-Benzenes Chemistry - A European Journal 17

Version of Record online: 22 MAR 2011 | DOI: 10.1002/chem.201002769

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Conjugated carbomers: “Weakly-capped” diethynylbutatrienes, the three-edge motifs of carbo-benzenes, are prepared by either reductive elimination from 3,6-dioxyocta-1,4,7-triyne precursors, or reductive coupling of gem-dihaloenyne moieties (see figure). Their spectroscopic and electrochemical properties are analyzed on the basis of the relative extent of conjugation.

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