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Dr. Cristina Tejel, Prof. Dr. Miguel A. Ciriano and Dr. Vincenzo Passarelli Rhodium(III)-Catalyzed Dimerization of Aldehydes to Esters Chemistry - A European Journal 17

Article first published online: 7 DEC 2010 | DOI: 10.1002/chem.201002921

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No sooner said than done: A rhodi- um(III) hydride complex is an outstandingly effective and selective catalyst for the dimerization of aldehydes to the corresponding esters (see scheme). Evidence for an unusual mechanism in catalysis by rhodium is given.

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