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Dr. Hongzhi Liu, Michael Puchberger and Ulrich Schubert A Facile Route to Difunctionalized Monosubstituted Octasilsesquioxanes Chemistry - A European Journal 17

Article first published online: 30 MAR 2011 | DOI: 10.1002/chem.201002940

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Make it POSS-ible: A series of novel difunctionalized monosubstituted polyhedral oligomeric silsesquioxanes (POSS) substituted with various functional organic groups (X) were synthesized from a mono(iodopropyl)-substituted T8 cluster (see scheme; R=iBu). These new cage compounds are versatile nanoscale building blocks for the preparation of organic–inorganic hybrid materials.

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