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Angel J. Jiménez, Dr. Bruno Grimm, Victoria L. Gunderson, Michael T. Vagnini, Sandra Krick Calderon, Dr. M. Salomé Rodríguez-Morgade, Prof. Dr. Michael R. Wasielewski, Prof. Dr. Dirk M. Guldi and Prof. Dr. Tomás Torres Synthesis, Characterization, and Photoinduced Energy and Electron Transfer in a Supramolecular Tetrakis (Ruthenium(II) Phthalocyanine) Perylenediimide Pentad Chemistry - A European Journal 17

Version of Record online: 22 MAR 2011 | DOI: 10.1002/chem.201002963

Thumbnail image of graphical abstract

Donor/acceptor hybrids: The supramolecular attachment of four RuII phthalocyanines to the 1,6,7,12-bay positions of a perylenediimide renders [PDIpy4{Ru(CO)Pc}4] (see figure), which shows strong electronic coupling between the donor [Ru(CO)Pc] and the acceptor PDIpy4 parts, in both the ground and excited states. Photoexcitation of either chromophore (see blue arrows for photoexcitation of [Ru(CO)Pc] and red arrows for photoexcitation of PDIpy4) produces a radical ion pair state.

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