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Dr. Masayoshi Nishiura, Dr. Jens Baldamus, Dr. Takanori Shima, Kyouichi Mori and Prof. Dr. Zhaomin Hou Synthesis and Structures of the C5Me4SiMe3-Supported Polyhydride Complexes over the Full Size Range of the Rare Earth Series Chemistry - A European Journal 17

Version of Record online: 1 APR 2011 | DOI: 10.1002/chem.201002998

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From two to eight! Tetranuclear octahydride complexes of a general formula [{(Cp′)Ln(μ-H)2}4(thf)x] (x=0, 1, 2; Cp′=C5Me4SiMe3) over the whole size range of the rare earth series have been obtained as self-assemblies of the dihydride species {(Cp′)LnH2}, resulting from the hydrogenolysis of their dialkyl precursors. The fine structures of these hydride clusters are dependent on the size of the metal ions. Some examples (core structures) are shown here.

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