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Norifumi Sakiyama, Daiki Hojo, Prof. Dr. Keiichi Noguchi and Prof. Dr. Ken Tanaka Enantioselective Synthesis of Axially Chiral 1-Arylisoquinolines by Rhodium-Catalyzed [2+2+2] Cycloaddition Chemistry - A European Journal 17

Article first published online: 5 JAN 2011 | DOI: 10.1002/chem.201003134

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It's all in the application! An enantioselective synthesis of axially chiral 1-arylisoquinolines has been achieved, which involves a rhodium-catalyzed [2+2+2] cycloaddition of diphenylphosphinoyl-substituted 1-arylisoquinolines (see scheme). The new diphenylphosphinoyl-substituted axially chiral 1-arylisoquinolines were successfully derivatized to the corresponding axially chiral P,N ligand and Lewis base catalyst.

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