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Dr. José Sánchez Costa, Gavin A. Craig, Dr. Leoní A. Barrios, Dr. Olivier Roubeau, Dr. Eliseo Ruiz, Silvia Gómez-Coca, Dr. Simon J. Teat and Dr. Guillem Aromí The Use of a Bis(phenylpyrazolyl)pyridyl Ligand to Prepare [Mn4] and [Mn10] Cage Complexes Chemistry - A European Journal 17

Article first published online: 25 MAR 2011 | DOI: 10.1002/chem.201003329

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Rational design versus serendipity: The first two high-nuclearity MnII/III clusters with a novel extended bis(phenylpyrazolyl)pyridyl ligand (see graphic) are described in a promising route for the preparation of new magnetic coordination aggregates, differing from conventional methods involving small bridging ligands.

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