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Dr. Yair Lavi, Dr. Ariela Burg, Dr. Eric Maimon and Prof. Dan Meyerstein Electron Exchange Columns through Entrapment of a Nickel Cyclam in a Sol–Gel Matrix Chemistry - A European Journal 17

Version of Record online: 4 APR 2011 | DOI: 10.1002/chem.201003451

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All change! An electron exchange column was developed by using the unique redox properties of nickel–cyclam and nickel–trans-III-meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane complexes and the physical and chemical stability of ceramic materials by using a sol–gel process to entrap the complexes. Parameters controlling the leaching were investigated. Redox cycles with the reducing agent ascorbic acid and persulfate as the oxidizing agent were performed.

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