Felix Gärtner, Albert Boddien, Enrico Barsch, Dr. Koichi Fumino, Dr. Sebastian Losse, Dr. Henrik Junge, Dr. Dirk Hollmann, Prof. Dr. Angelika Brückner, Prof. Dr. Ralf Ludwig and Prof. Dr. Matthias Beller Photocatalytic Hydrogen Generation from Water with Iron Carbonyl Phosphine Complexes: Improved Water Reduction Catalysts and Mechanistic Insights Chemistry - A European Journal 17
Version of Record online: 19 APR 2011 | DOI: 10.1002/chem.201003564
Reduced circumstances: Turnover numbers of up to 1600 and an incident photon-to-hydrogen efficiency of 13.4 % were achieved with an iron-based water-reduction catalyst combined with an iridium photosensitizer (see picture). Mechanistic investigations were carried out by NMR and in situ FTIR spectroscopy and DFT calculations. [HFe3(CO)11]− was identified as the active iron species during photocatalytic hydrogen evolution from water.
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