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Lan-Gui Xie and Prof. Dr. Zhong-Xia Wang Cross-Coupling of Aryl/Alkenyl Ethers with Aryl Grignard Reagents through Nickel-Catalyzed C[BOND]O Activation Chemistry - A European Journal 17

Version of Record online: 1 MAR 2011 | DOI: 10.1002/chem.201003731

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The formation of a C[BOND]C bond has been achieved through the cleavage of the sp2 C[BOND]O bond of aryl/alkenyl ethers catalyzed by a nickel complex, and by using Grignard reagents as nucleophiles (see scheme). This method displays a broad substrate scope and leads to good to excellent yields of the aryl–aryl or alkenyl–aryl cross-coupling products.

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