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Dr. Ibrahim Abdellah, Dr. Martial Boggio-Pasqua, Dr. Yves Canac, Dr. Christine Lepetit, Carine Duhayon and Prof. Remi Chauvin Towards the Limit of Atropochiral Stability: H-MIOP, an N-Heterocyclic Carbene Precursor and Cationic Analogue of the H-MOP Ligand Chemistry - A European Journal 17

Article first published online: 23 MAR 2011 | DOI: 10.1002/chem.201100205

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MIOP-ic view: The enantiospecific preparation of H-MIOP, an atropochiral N-heterocyclic carbene (NHC)–phosphine ligand precursor and cationic analogue of the H-MOP ligand (see scheme; Tr=racemization temperature), is reported. The configurational stability of (R)- and (S)-H-MIOP furthers the fundamental appraisal of molecular atropochirality.

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