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Dr. Roberto Martin, Dr. Sergio Navalon, Dr. Juan Jose Delgado, Dr. Jose J. Calvino, Prof. Mercedes Alvaro and Prof. Hermenegildo Garcia Influence of the Preparation Procedure on the Catalytic Activity of Gold Supported on Diamond Nanoparticles for Phenol Peroxidation Chemistry - A European Journal 17

Article first published online: 15 JUL 2011 | DOI: 10.1002/chem.201100955

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Size really matters: The activity of different diamond-supported gold nanoparticle (Au/D) samples has been correlated with the reduction treatment used. These catalysts have been tested in a heterogeneous Fenton-like reaction, which established that the most active material is the one prepared at pH 5 followed by subsequent thermal treatment at 300 °C under hydrogen (see scheme).

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