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Zulema Arcis-Castíllo, Sipeng Zheng, Dr. Maxime A. Siegler, Dr. Olivier Roubeau, Salma Bedoui and Dr. Sylvestre Bonnet Tuning the Transition Temperature and Cooperativity of bapbpy-Based Mononuclear Spin-Crossover Compounds: Interplay between Molecular and Crystal Engineering Chemistry - A European Journal 17

Version of Record online: 1 DEC 2011 | DOI: 10.1002/chem.201101301

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A model of cooperativity: The spin-crossover properties of different isomers of substituted spin-crossover compounds [Fe{R2(bapbpy)}(NCS)2] are presented. Both the cooperativity and transition temperature critically depend on the position of the substituents R on the terminal pyridine rings of the ligand (see figure); a simple model based on hydrogen-bonding networks is provided.

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