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Dr. Swapna Ganapathy, Dr. Ernst R. H. van Eck, Prof. Dr. Arno P. M. Kentgens, Prof. Dr. Fokko M. Mulder and Dr. Marnix Wagemaker Equilibrium Lithium-Ion Transport Between Nanocrystalline Lithium-Inserted Anatase TiO2 and the Electrolyte Chemistry - A European Journal 17

Article first published online: 25 NOV 2011 | DOI: 10.1002/chem.201101431

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Lithium-ion transport: The exchange of lithium ions across the solid/electrolyte interface (SEI) between an electrolyte and a lithium-inserted TiO2 anatase electrode has been studied by using 7Li NMR spectroscopy (see figure). The barrier to lithium-ion transport across the SEI depends on the composition of the electrolyte; this indicates that the SEI can form a rate-limiting barrier.

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