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Sebastian C. Junggeburth, Katharina Schwinghammer, Kulpreet S. Virdi, Prof. Dr. Christina Scheu and Prof. Dr. Bettina V. Lotsch Towards Mesostructured Zinc Imidazolate Frameworks Chemistry - A European Journal 18

Version of Record online: 9 JAN 2012 | DOI: 10.1002/chem.201101530

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The structural analogy between microporous ZIFs and zeolites has been demonstrated to also hold for mesostructured silica materials on the one hand, and mesostructured imidazolate frameworks (MIFs) on the other (see figure). Comprehensive characterization of the obtained MIF materials gives evidence of a lamellar hybrid structure composed of bromine-terminated zinc imidazolate chains, which are sandwiched by cationic surfactant layers.

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